FULLERENES
Fullerenes are carbon nanostructures which
include nanotubes and bucky balls (more properly known as buckminsterfullerene,
are spherical molecules composed entirely of carbon atoms). Synthesised by the
condensation of high-temperature carbon
vapour, they have diameters ranging from a fraction of a nanometre to 100 nm.
This is the material of the future with extraordinary properties to match.
Carbon nanotubes, for example, conduct much better than copper and are 100
times stronger than steel, but one-sixth of the weight.
Applications: electronics, energy devices, highstrength
materials, super-sensitive nano-sensors and ideal for catalyst support.
NANO DRUG ENCAPSULATION
Using a chemical process, drugs are
encapsulated in biodegradable-polymer capsules 100 to 500 nm in diameter. Due
to their small size the capsules are taken up by cells. The benefit is a
reduction in dose frequency of medication due to the slow release of the drug.
Applications: delivery of TB, HIV/Aids and malaria drugs.
QUANTUM DOTS
A quantum dot is a semi-conductor (between
conductor and insulator) with nano-dimensions. Quantum dots and nano phosphors
exhibit unique optical, magnetic and electronic properties, due to the quantum
confinement effect. Depending on their size, they absorb and emit different
colours when irradiated with photons or
electrons.
Applications: used in biosensors which can be used to
pinpoint disease in the body, solar cells and flat panel displays and special coatings.
NANO COMPOSITES
By adding nanoparticles and nanostructures to
a polymer, a nanocomposite is formed. These materials of the future can be
super-strong, light, conducting and transparent. A nanocomposite can be much
more transparent than a polymer containing
micron particles, which is opaque.
Applications: aeronautic and automobile industries
scratch-resistant coatings; self-cleaning windows, fuel cells.
NANOPARTICLES
Nanoparticles can be produced chemically in
high temperature reactors or through mechanical milling. They are mostly 10 to
100 nm in diameter and often agglomerated.
Applications: coatings, composites, solar cells and
medicine. Silicon nanoparticles can be used for printed electronics3.
WATER PURIFICATION
Nanotechnology offers a low-cost and
effective solution to the challenge of access to clean and safe water for
millions of people in South Africa and the developing world. The technology
holds the potential to radically reduce the number of steps,
materials and energy needed to purify water.
Depending on the kind of water to be purified – ground, surface or waste water
– nano-materials can be tailor-made with specific pore sizes and large enhanced
surface areas to filter out certain unwanted
pollutants, such as heavy metals or biological
toxins. For example, titanium oxide at nanoscale can be used to degrade organic
pollutants. And silver nano-particles have the ability to degrade biological
pollutants such as bacteria.
South African scientists are testing
different kinds of membranes and filters based on carbon nanotubes, nanoporous
ceramics, magnetic nano-particles and other nano-materials which could be used
to remove water-borne diseases such as typhoid and cholera, as well as toxic
metal ions, organic and inorganic solutes.
When coated with different compounds could be
used to remove pollutants, including arsenic, from water.
Nanosensors – Researchers are developing new
sensor technologies that combine micro- and nanofabrication technology to
create small, portable, and highly accurate sensors to detect chemical and
biochemical parameters in water. Several research consortia are field testing
devices that incorporate nanosensor technology to detect pollutants in water,
and some expect to commercialize these devises.
HEALTH
In both diagnosis and treatment,
nanotechnology holds the key to revolutionise health care, particularly in
developing countries where access to effective health care is still a challenge
for millions of people living in remote areas. In the field of diagnostics,
nanotechnology promises quick, early and accurate detection of diseases.
Portable, but highly sensitive point-of-care
test kits are under development which will offer all the diagnostic functions
of a medical laboratory. Depending on how they are designed and the intended
application, the hand held kits could be used to test for viruses, bacteria or
hormones. Thus they will be able to test – simply and quickly – for infectious
diseases such as malaria, cholera, HIV/Aids and other sexually-transmitted
infections, and even cancer. Also known as the “lab-on-a-chip” because of their
ability to emulate the services of a complete medical laboratory, these
inexpensive, hand-held diagnostic kits can pick up the presence of several
pathogens at once and could be used for wide-ranging screening in remote
clinics.
Biomedical imaging – Nanotechnology
applications are in development that will radically improve medical imaging
techniques.
For example, gold and silver nanoparticles
have optical properties which make them extremely effective as contrast agents.
Quantum dots which are brighter than organic dyes and need only one light
source for excitation, when used in conjunction with magnetic resonance
imaging, can produce exceptional images of tumour sites.
Nanomaterials are also used in therapeutics
or treatment: Targeted drug delivery systems – Nanostructures can be used to
recognise diseased cells and to deliver drugs to the affected areas to combat
cancerous tumours, for example, without harming healthy cells. In obesity, nano
--particles can target and inhibit the growth of fat deposits.
Slow-release drug therapy – Research shows
that nano-sized biodegradable polymer capsules containing drugs for
tuberculosis treatment are effectively taken up by the body’s cells.
The effect is a slower release of the drug
into the body and a reduction in the frequency with which TB patients need to
take his or her medication. In countries where drugs are not readily available
and compliance is generally low due to a number of reasons, the technology
holds great potential for increased drug compliance and less chance of the
development of drug resistance. Photothermal and hypothermal destruction of
cancer – Some nanoparticles, such as gold, possess therapeutic properties based
on their magnetic wavelength or optical properties. They absorb light and heat
up the surrounding area, killing the cancer cells.
ENERGY
Another impressive application for
nanotechnology is energy production, conversion and storage. Research is well
advanced enough to establish that nanotechnology offers a viable alternative to
non-renewable fossil-fuel consumption and gives us the means to achieve a
“hydrogen economy”. Nano-applications in this area include: solar cells; fuel
cells and new energy production, conversion and storage processes. In all
cases, the results are energy that is cheaper, cleaner, more efficient and
renewable. In future, nano holds the potential to produce hybrid vehicles with
reduced fuel consumption and a lighter motor weight.
INDUSTRIAL APPLICATIONS
Nanotechnology is set to add value to South Africa’s
raw mineral resources through beneficiation of gold, platinum group metals and
other minerals which are used as high performance catalysts, absorbents in
polymer nano composites and in energy-saving materials.
Nanotechnology can produce cleaner process engineering
which will in turn produce value-added chemicals and speciality products,
including bio catalytic systems and
novel heterogeneous catalysts. Nanotechnology can make catalytic converters
more efficient, cheaper and more accurately controlled. l Nanotechnology-based
innovations can be designed that will combat air pollution remediation, detect toxic
materials and leaks, reduce fossil fuel emissions and separate gases.
Advanced materials and
manufacturing applications – the list is endless …
Nanotechnology can produce smart, functional materials,
including lubricants and barrier coatings, ultra-hard and super-strong
materials, electro and photo-chromic materials with applications in all manufacturing
sectors, industry, medical and
domestic markets. Nanoparticles can also
improve a wide range of properties shown by engineering plastics, such as
bio-degradability and improved thermal, mechanical and electrical properties. Thus,
plastic bags can be made to bio-degrade and
plastic car parts or building materials can
be made more fire-resistant. Other areas include the development of
nanoparticles for applications in phosphorous paints, printable electronics, inexpensive
solar cells and nanotube synthesis for application in sensors and as catalyst
support structures.
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